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The effects of charge dilution on low-temperature diesel combustion and emissions were investigated in a small-bore single-cylinder diesel engine over a wide range of injection timing. The fresh air was diluted with additional N2 and CO2, simulating 0 to 65% exhaust gas recirculation in an engine. Diluting the intake charge lowers the flame temperature T due to the reactant being replaced by inert gases with increased heat capacity. In addition, charge dilution is anticipated to influence the local charge equivalence ratio ϕ prior to ignition due to the lower O2 concentration and longer ignition delay periods. By influencing both ϕ and T, charge dilution impacts the path representing the progress of the combustion process in the ϕ-T plane, and offers the potential of avoiding both soot and NOx formation.

Fuel tracer-based planar laser-induced fluorescence is used to investigate the vaporization and mixing behavior of pilot injections for variations in pilot mass of 1-4 mg, and for two injection pressures, two near-TDC ambient temperatures, and two swirl ratios. The fluorescent tracer employed, 1-methylnaphthalene, permits a mixture of the diesel primary reference fuels, n-hexadecane and heptamethylnonane, to be used as the base fuel. With a near-TDC injection timing of −15°CA, pilot injection fuel is found to penetrate to the bowl rim wall for even the smallest injection quantity, where it rapidly forms fuel-lean mixture. With increased pilot mass, there is greater penetration and fuel-rich mixtures persist well beyond the expected pilot ignition delay period. Significant jet-to-jet variations in fuel distribution due to differences in the individual jet trajectories (included angle) are also observed.

This study summarizes the peer-reviewed literature regarding the use of raw pyrolysis liquids (PLs) created from woody biomass as fuels for compression-ignition (CI) engines. First, a brief overview is presented of fast pyrolysis and the potential advantages of PLs as fuels for CI engines. Second, a discussion of the general composition and properties of PLs relative to conventional, petroleum-derived diesel fuels is provided, with emphasis on the differences that are most likely to affect PL performance in CI-engine applications. Next, a synopsis is given of the peer-reviewed literature describing experimental studies of CI engines operated using neat PLs and PLs combined in various ways with other fuels. This literature conclusively indicates that raw PLs and PL blends cannot be used as “drop-in replacements” for diesel fuel in CI engines, which is reflected in part by none of the cited studies reporting successful operation on PL fuels for more than twelve consecutive hours.

This work investigates the impact of injector temperature on the characteristics of high-pressure n-dodecane sprays under conditions relevant to heavy-duty diesel engines. Sprays are injected from a pair of single-hole diesel injectors belonging to the family of “Spray C” and “Spray D” Engine Combustion Network (ECN) injectors. Low and high injector temperature conditions are achieved by activating or deactivating a cooling jacket. We quantify spray spreading angle and penetration using high-speed shadowgraphy and long-distance microscopy imaging. We evaluate differences in fuel/air mixture formation at key timings through one-dimensional modeling. Injections from a cooled injector penetrate faster than those from a higher temperature injector, especially for an injector already prone to cavitation (Spray C).

The effects of injection timing and diluent addition on the late-combustion soot burnout in a direct-injection (DI) diesel engine have been investigated using simultaneous planar imaging of the OH-radical and soot distributions. Measurements were made in an optically accessible DI diesel engine of the heavy-duty size class at a 1680 rpm, high-load operating condition. A dual-laser, dual-camera system was used to obtain the simultaneous “single-shot” images using planar laser-induced fluorescence (PLIF) and planar laser-induced incandescence (PLII) for the OH and soot, respectively. The two laser beams were combined into overlapping laser sheets before being directed into the combustion chamber, and the optical signal was separated into the two cameras by means of an edge filter.

Engine-out CO emission and fuel conversion efficiency were measured in a highly-dilute, low-temperature diesel combustion regime over a swirl ratio range of 1.44-7.12 and a wide range of injection timing. At fixed injection timing, an optimal swirl ratio for minimum CO emission and fuel consumption was found. At fixed swirl ratio, CO emission and fuel consumption generally decreased as injection timing was advanced. Moreover, a sudden decrease in CO emission was observed at early injection timings. Multi-dimensional numerical simulations, pressure-based measurements of ignition delay and apparent heat release, estimates of peak flame temperature, imaging of natural combustion luminosity and spray/wall interactions, and Laser Doppler Velocimeter (LDV) measurements of in-cylinder turbulence levels are employed to clarify the sources of the observed behavior.

Prior studies have shown that fuel addition during negative valve overlap (NVO) can both increase temperature and alter composition of the charge carried over to main HCCI combustion. Late NVO fuel injection, i.e., near top dead center, can cause piston wetting and subsequent localized rich flames. Since acetylene is a product of rich combustion and is known to advance ignition, it is hypothesized that the species could play a chemical role in enhancing main combustion. The objective of this work is to quantify the effects of acetylene on HCCI combustion. While the research topic is specifically relevant to NVO-fueled HCCI operation, the experiments are conducted without NVO fueling to avoid uncertainties of NVO reforming reactions. Instead, a single post-NVO injection of iso-octane fuels the cycle, and acetylene is seeded into the intake flow at varying concentrations to simulate a reformed product of NVO.

Within the Engine Combustion Network (ECN) spray combustion research frame, simultaneous line-of-sight laser extinction measurements and laser-induced incandescence (LII) imaging were performed to derive the soot volume fraction (fv). Experiments are conducted at engine-relevant high-temperature and high-pressure conditions in a constant-volume pre-combustion type vessel. The target condition, called "Spray A," uses well-defined ambient (900 K, 60 bar, 22.8 kg/m₃, 15% oxygen) and injector conditions (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K). Extinction measurements are used to calibrate LII images for quantitative soot distribution measurements at cross sections intersecting the spray axis. LII images are taken after the start of injection where quasi-stationary combustion is already established.

Soot formation in high-pressure n-dodecane sprays is investigated under conditions relevant to heavy-duty diesel engines. Sprays are injected from a single-hole diesel injector belonging to the family of engine combustion network (ECN) Spray D injectors. Soot is quantified using a high-speed extinction imaging diagnostic with incident light wavelengths of 623 nm and 850 nm. Previously, soot measurements in a high-pressure spray using 406-nm and 520-nm incident light demonstrated a minimal wavelength dependence in the complex refractive index of soot (m), as demonstrated by a near unity ratio of the non-dimensional extinction coefficients (ke,406 nm/ke,520 nm). The present work, however, demonstrates a significant difference in m for measurements with infrared incident light. During the quasi-steady period of the spray combustion event, the experimentally determined ke ratio (ke,623 nm/ke,850 nm) is 1.42 ± 0.27.

The spatial and temporal locations of autoignition depend on fuel chemistry and the temperature, pressure, and mixing trajectories in the fuel jets. Dual-fuel systems can provide insight into fuel-chemistry aspects through variation of the proportions of fuels with different reactivities, and engine operating condition variations can provide information on physical effects. In this context, the spatial and temporal progression of two-stage autoignition of a diesel-fuel surrogate, n-heptane, in a lean-premixed charge of synthetic natural gas (NG) and air is imaged in an optically accessible heavy-duty diesel engine. The lean-premixed charge of NG is prepared by fumigation upstream of the engine intake manifold.

Sources of unburned hydrocarbon (UHC) emissions are examined for a highly dilute (10% oxygen concentration), moderately boosted (1.5 bar), low load (3.0 bar IMEP) operating condition in a single-cylinder, light-duty, optically accessible diesel engine undergoing partially-premixed low-temperature combustion (LTC). The evolution of the in-cylinder spatial distribution of UHC is observed throughout the combustion event through measurement of liquid fuel distributions via elastic light scattering, vapor and liquid fuel distributions via laser-induced fluorescence, and velocity fields via particle image velocimetry (PIV). The measurements are complemented by and contrasted with the predictions of multi-dimensional simulations employing a realistic, though reduced, chemical mechanism to describe the combustion process.

Future fuels will come from a variety of feed stocks and refinement processes. Understanding the fundamentals of combustion and pollutants formation of these fuels will help clear hurdles in developing flex-fuel combustors. To this end, we investigated the combustion, soot formation, and soot oxidation processes for various classes of fuels, each with distinct physical properties and molecular structures. The fuels considered include: conventional No. 2 diesel (D2), low-aromatics jet fuel (JC), world-average jet fuel (JW), Fischer-Tropsch synthetic fuel (JS), coal-derived fuel (JP), and a two-component surrogate fuel (SR). Fuel sprays were injected into high-temperature, high-pressure ambient conditions that were representative of a practical diesel engine. Simultaneous laser extinction measurement and planar laser-induced incandescence imaging were performed to derive the in-situ soot volume fraction.

Experiments were conducted in an optically accessible constant-volume combustion vessel to investigate soot formation at diesel combustion conditions in a high exhaust-gas recirculation (EGR) environment. The ambient oxygen concentration was decreased systematically from 21% to 8% to simulate a wide range of EGR conditions. Quantitative measurements of in-situ soot in quasi-steady n-heptane and #2 diesel fuel jets were made by using laser extinction and planar laser-induced incandescence (PLII) measurements. Flame lift-off length measurements were also made in support of the soot measurements. At constant ambient temperature, results show that the equivalence ratio estimated at the lift-off length does not vary with the use of EGR, implying an equal amount of fuel-air mixing prior to combustion. Soot measurements show that the soot volume fraction decreases with increasing EGR.

Ethanol and ethanol/gasoline blends are being widely considered as alternative fuels for light-duty automotive applications. At the same time, HCCI combustion has the potential to provide high efficiency and ultra-low exhaust emissions. However, the application of HCCI is typically limited to low and moderate loads because of unacceptably high heat-release rates (HRR) at higher fueling rates. This work investigates the potential of lowering the HCCI HRR at high loads by using partial fuel stratification to increase the in-cylinder thermal stratification. This strategy is based on ethanol's high heat of vaporization combined with its true single-stage ignition characteristics. Using partial fuel stratification, the strong fuel-vaporization cooling produces thermal stratification due to variations in the amount of fuel vaporization in different parts of the combustion chamber.

The reaction zone of a diesel fuel jet stabilizes at a location downstream of the fuel injector once the initial autoignition phase is over. This distance is referred to as flame lift-off length. Recent investigations have examined the effects of a wide range of parameters (injection pressure, orifice diameter, and ambient gas temperature, density and oxygen concentration) on lift-off length under quiescent diesel conditions. Many of the experimental trends in lift-off length were in agreement with scaling laws developed for turbulent, premixed flame propagation in gas-jet lifted flames at atmospheric conditions. However, several effects did not correlate with the gas-jet scaling laws, suggesting that other mechanisms could be important to lift-off stabilization at diesel conditions. This paper shows experimental evidence that ignition processes affect diesel lift-off stabilization.

This study presents estimates for measurement uncertainties for a Homogenous Charge Compression Ignition (HCCI)/Low-Temperature Gasoline Combustion (LTGC) engine testing facility. A previously presented framework for quantifying those uncertainties developed uncertainty estimates based on the transducers manufacturers’ published tolerances. The present work utilizes the framework with improved uncertainty estimates in order to more accurately represent the actual uncertainties of the data acquired in the HCCI/LTGC laboratory, which ultimately results in a reduction in the uncertainty from 30 to less than 1 kPa during the intake and exhaust strokes. Details of laboratory calibration techniques and commissioning runs are used to constrain the sensitivities of the transducers relative to manufacturer supplied values.

A new diagnostic technique is described that has the capability of making real-time, in situ measurements of the volatile fraction of diesel particulate matter (PM). LIDELS uses two laser pulses of comparable energy, separated in time by an interval sufficiently short to freeze the flow field, to measure the change in PM volume caused by laser-induced desorption of the volatile fraction. The first laser pulse produces elastic light scattering (ELS) that gives the volume of the total PM, and also deposits the energy to desorb the volatiles. ELS from the second pulse gives the volume of the remaining solid portion of the PM, and the ratio of these two measurements is the quantitative solid volume fraction. Calibration is required for the individual total PM and solid fraction to be quantitative. Applicability of the technique is demonstrated for load and EGR sweeps for a turbocharged, direct-injection diesel engine.

This paper details the development and application of a Rayleigh imaging technique for quantitative mixing measurements in a vaporizing diesel spray under engine conditions. Experiments were performed in an optically accessible constant-volume combustion vessel that simulated the ambient conditions in a diesel engine. Two-dimensional imaging of Rayleigh scattering from a diesel spray of n-heptane and well-characterized ambient was accomplished by using a 532 nm Nd:YAG laser sheet and a low-noise back-illuminated CCD camera. Methods to minimize interference from unwanted elastic scattering sources (e.g. windows, particles) were investigated and are discussed in detail. The simultaneous measurement of Rayleigh scattering signal from the ambient and from the diesel spray provides important benefits towards making the technique quantitative and accurate.

Line-imaging of Raman scattered light is used to simultaneously measure the mole fractions of CO2, H2O, N2, O2, and fuel (premixed C3H8) in a modern 4-valve spark-ignition engine operating at idle. The measurement volume consists of 16 adjacent sub-volumes, each 0.27 mm in diameter × 0.91 mm long, giving a total measurement length of 14.56 mm. Measurements are made 3 mm under the centrally-located spark plug, offset 3 mm from the spark plug center towards the exhaust valves. Data are taken in 15 crank angle degree increments starting from top center before the intake stroke (-360 CAD) through top center of the compression stroke (0 CAD).

Laser-induced incandescence (LII) is a sensitive diagnostic technique capable of making exhaust particulate-matter measurements during transient operating conditions. This paper presents measurements of LII signals obtained from the exhaust gas of a 1.9-L TDI diesel engine. A scanning mobility particle sizer (SMPS) is used in fixed-size mode to obtain simultaneous number concentration measurements in real-time. The transient studies presented include a cranking-start/idle/shutdown sequence, on/off cycling of EGR, and rapid load changes. The results show superior temporal response of LII compared to the SMPS. Additional advantages of LII are that exhaust dilution and cooling are not required, and that the signal amplitude is directly proportional to the carbon volume fraction and its temporal decay is related to the primary particle size.